State-to-State Dynamical Research in the F H2 Reaction System By: Zefeng Ren Publisher: Springer Print ISBN: 9783642397554, 3642397557 eText ISBN: 9783642397561, 3642397565 Copyright year: 2014 Format: EPUB Available from $ 99.00 USD SKU 9783642397561 This thesis addresses two important and also challenging issues in the research of chemical reaction dynamics of F H2 system. One is to probe the reaction resonance and the other is to determine the extent of the breakdown of the Born-Oppenheimer approximation (BOA) experimentally. The author introduces a state-of-the-art crossed molecular beam-scattering apparatus using a hydrogen atom Rydberg tagging time-of-flight method, and presents thorough state-to-state experimental studies to address the above issues. The author also describes the observation of the Feshbach resonance in the F H2 reaction, a precise measurement of the differential cross section in the F HD reaction, and validation of a new accurate potential energy surface with spectroscopic accuracy. Moreover, the author determines the reactivity ratio between the ground state F(2P3/2) and the excited state F*(2P1/2) in the F D2 reaction, and exploits the breakdown of BOA in the low collision energy. Download eBook Free: https://ouo.io/6FpUoP
